CHEM 1364 Test 3 Fall 1997


SHORT ANSWER: 2 points each. Fill in the blank with the most correct answer.

1. The ___________________ of light is the number of times the light 'wave' undergoes a complete oscillation per second.

2. The ___________________ Effect, in which electrons are ejected from a metal by some frequencies of light but not others, was the first bit of evidence pointing to the 'dual nature' of light.

3. _________________ can be considered to be massless 'particles' of light.

4. An electron in a(n) ________________ state is in an 'unnatural' condition, and must eventually lose energy to return to the ground state.

5. The _____________ spectra that we observed from the gas discharge tubes occurred because of the return of these electrons to a lower energy state.

6. These spectra in (6) are evidence for _________________ of energy levels - or the fact that only certain energy states are allowed.

7. Name two regions of the electromagnetic spectrum other than visible light:

_________________________ and ________________________.

8. A(n) ______________ is a three dimensional probability function for an electron.

9. The ____________________ Uncertainty Principle, which states that we cannot know both the position and momentum of an electron.

10. ___________________ electrons are the electrons in the outermost s and p subshells, plus any electrons in unfilled d or f subshells.

11. A(n) ___________________ configuration of the electrons occurs when the outer s and p subshells are completely filled, and any inner subshells are either completely filled or completely empty.

12. A species will be _________________ if there are any unpaired electrons in orbitals.

13. Species that are _________________ have identical electronic structures.

14. _________________ are those species that exhibit characteristics between those of metals and non-metals.

15. The 'family' name for the elements in Group VIIA is the _________________.


PROBLEMS (Point totals are shown in parenthesis). Show your work and circle your answers where appropriate for full credit.

16. (15) Calculate the energy, frequency, and the wavelength (in nm) for a photon that is produced when an electron falls from the n = 6 to the n = 2 energy level in hydrogen.

17. (10) Light emitted by the fluorescence of fluorescein has an energy of 230 kJ/mol. Calculate the wavelength of this light in nm.

18. (15) Write the complete electronic structure for the following atoms and ions:

Mn

Xe

Ho

Ga3+

Se2-

19. (15) List a correct set of values of the quantum numbers for each of the valence electrons (in the ground state configuration) for the following atoms:

Al

Tc

Pr

20. (15) Arrange the following groups of atoms/ions in order of increasing size.

K, Cs, Li, K, Na

Ge, F, S, As, In

S2-, Ca2+, Ar, Be2+, Se2-

EXTRA CREDIT (10) Explain, from an electronic configuration standpoint, why silver is one of the few 'transition' elements that does not form a +2 charged ion.


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